If you are unable to create database users in Plesk and displaying the errors as follows upon creation:
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Error: Connection to the database server has failed:
Table ‘mysql.servers’ doesn’t exist
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This error generally occurs while compiling MySQL to new version, apparently due to incomplete MySQL upgrade.
So give the following from shell as root to solve the issue.
mysql_fix_privilege_tables --user=admin --password=<admin password> --verbose
Replace <admin password> with the exact password.